Adult trombiculids are free-living (feeding on plant material), and not parasitic like the larvae (just-hatched life stage). You can easily check this by counting the pairs of legs. Four pairs means it's an adult or nymph, three pairs means it's a larva.
You could oven-bake to sterilize your bark and substrate, since these guys may reproduce and you could end up with parasitic larvae (although I don't think that they typically prey on amphibians (except toads?), which are not appealing to a lot of ectoparasites thanks to their skin secretions). This could kill off beneficial bacteria in your substrate, though.
I certainly wouldn't use any pesticide out of fear of toxicity to your Slimies.