I'm not sure how to check the limestone content either. I think if you have a lot of limestone in the area (a pale coloured rock), it would be safe to assume that you have some in and around your well or at least that it would be affecting the water in the well. It's not harmful, it just buffers the pH high. If the alkalinity is high, you can still overcome the high pH, it just takes more chemicals (an acid - you can buy pH down but you'll have to add a bunch of drops). Basically, there are carbonate ions in the water causing the pH to be higher. To reduce the pH, you have to 'use up' the carbonate ions by adding in an acidic substance. The hydrogen ions (H+) from the acid will give you a lower pH as you use up the carbonate. The trick here is that the pH will remain relatively constant until you overcome all the carbonate ions, then it will plummet sharply. You will probably have to add a fair amount of pH down. As a result, if you are going to try to reduce the pH in your water, you will have to monitor very closely as you add in pH down. It's still do-able, but you might want to get your pH stable before adding in your critters.